Ferrocene-type Polymers
نویسندگان
چکیده
منابع مشابه
Ring Rotation in Ferrocene and Ferrocene-containing Polymers
Ferrocene is an organometallic molecular sandwich complex with an iron atom coordinated between two cyclopentadienyl rings. The reorientation of these rings in a process of rotational jump diffusion between multiple equilibrium sites on a circle is investigated using quasielastic neutron time of flight and backscattering spectroscopy experiments. Existing results on the ring rotation in bulk, c...
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Nuzhath Ahmed Abstract Ferrocene is frequently used in polymer chains owing to their electrochemical properties. The paper aims at identifying novel routes to synthesize a dinuclear complex 1.pyz.1 and a poly [2.pyz]n. The complex 1.pyz.1 is synthesized from the reaction of pyrazine with solution of 1 while the poly is obtained from the reaction of solution of 2 with pyrazine. Following the syn...
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The reaction of 1,1'-ferrocenedicarboxylic acid (LH(2)) with bis(triphenyltin) oxide afforded a molecular heterobimetallic compound [(Ph(3)Sn)(2)L]. In the latter the two carboxylate units of [L](2-) are involved in an anisobidentate chelating coordination mode to two triphenyl tin units. The reaction of LH(2) with trimethyltin hydroxide or bis(tri-n-butyltin) oxide afforded 2D-coordination pol...
متن کاملAntibacterial activity of soluble pyridinium-type polymers.
Cross-linked poly(N-benzyl-4-vinylpyridinium halide) (designated insoluble BVP) was previously reported to capture bacterial cells alive by contact with them. The corresponding linear polymer poly(N-benzyl-4-vinylpyridinium salt) (designated soluble BVP) was found to exhibit antibacterial activity. This soluble pyridinium-type polymer showed strong antibacterial activity against gram-positive b...
متن کامل(2,2-Dichlorovinyl)ferrocene
The title compound, [Fe(C(5)H(5))(C(7)H(5)Cl(2))], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclo...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1968
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.26.1018